Following is the explanation regarding particles in Nirukta - Chapter 1, Section 4:
Particles (निपात) occur in various senses: in a comparative sense (उपमार्थ), in a conjunctive sense (कर्मोपसंग्रहार्थ), and as expletives (पदपूरणः).
Of them, the following four are used in the sense of comparison (उपमार्थ):
1. ‘इव’ (iva) - in classical Sanskrit (भाषा) as well as in Vedic Sanskrit (अन्वध्यायं) – “अग्निरिव” (Like Agni), "इंद्र इव" (Like Indra)
2. ‘न’ (na) has the sense of negation (प्रतिषेधार्थ) in classical Sanskrit, and both the sense of negation and comparison (उपमार्थ) in Vedic Sanskrit – “नेन्द्रं देवममंसत्” (They did not recognize Indra as a god)
The established use is to place it immediately before that which it makes negative and to place it immediately after that with which it compares – “दुर्मदासो न सुरायाम्” (Like hard drinkers of wine) – here it has the sense of comparison.
3. ‘चिद्’ (cid) has many meanings:
a. In the sentence - “आचार्यश्र्चिदिदं ब्रूयात्” (Will the teacher kindly explain it?) - it is used in the sense of respect (पूजायाम्)

From what root is the word ‘आचार्य’ (ācārya, teacher) derived?
i. आचारं ग्राहयति – He makes one understand way to act (ācāra)
ii. आचिनोत्यर्थान् – He holds (ācinoti) the knowledge
iii. आचिनोति बुद्धिमिति – he develops (ācinoti) the mind (of the student)
b. In the expression - “दधिचित्” (like curd) - it is used in the sense of comparison (उपमार्थ)
c. In “कुल्माषांश्र्चिदाहर” (bring even the inferior grain)- it is used in the sense of contempt (अवकुत्सिते)
'कुल्मार्षाः' (kulmārṣāḥ, inferior grain) is so called because it is left behind by families - कुल्मार्षाः कुलेषु सीदन्ति
a. In the sentence- “इदं नु करिष्यति” (therefore he will do it) - it is used for assigning a reason (हेत्वपदेशे)
b. In “कथं नु करिष्यति” (how pray will he do it?), “नन्वेतदकार्षीत्” (has he really done it?) - it is used for asking a question (अनुपृष्ट)
c. In - “वृक्षस्य नु ते पुरुहूत् वयाः” (Of thee like the branches of a tree) - it is used in a sense of comparison (उपमार्थ)
'वयाः' (vayāḥ) means branch, it has the sense of movement from ‘वी’ (vī) because a branch moves in the wind - वयाः शाखा वेतेः I वातायना भवन्ति
'शाखा' (śākhā, branches) are so called because they rest in the sky - शाखाः खशयाः
Particles (निपात) occur in various senses: in a comparative sense (उपमार्थ), in a conjunctive sense (कर्मोपसंग्रहार्थ), and as expletives (पदपूरणः).
Of them, the following four are used in the sense of comparison (उपमार्थ):
1. ‘इव’ (iva) - in classical Sanskrit (भाषा) as well as in Vedic Sanskrit (अन्वध्यायं) – “अग्निरिव” (Like Agni), "इंद्र इव" (Like Indra)
2. ‘न’ (na) has the sense of negation (प्रतिषेधार्थ) in classical Sanskrit, and both the sense of negation and comparison (उपमार्थ) in Vedic Sanskrit – “नेन्द्रं देवममंसत्” (They did not recognize Indra as a god)
The established use is to place it immediately before that which it makes negative and to place it immediately after that with which it compares – “दुर्मदासो न सुरायाम्” (Like hard drinkers of wine) – here it has the sense of comparison.
3. ‘चिद्’ (cid) has many meanings:
a. In the sentence - “आचार्यश्र्चिदिदं ब्रूयात्” (Will the teacher kindly explain it?) - it is used in the sense of respect (पूजायाम्)

From what root is the word ‘आचार्य’ (ācārya, teacher) derived?
i. आचारं ग्राहयति – He makes one understand way to act (ācāra)
ii. आचिनोत्यर्थान् – He holds (ācinoti) the knowledge
iii. आचिनोति बुद्धिमिति – he develops (ācinoti) the mind (of the student)
b. In the expression - “दधिचित्” (like curd) - it is used in the sense of comparison (उपमार्थ)
c. In “कुल्माषांश्र्चिदाहर” (bring even the inferior grain)- it is used in the sense of contempt (अवकुत्सिते)
'कुल्मार्षाः' (kulmārṣāḥ, inferior grain) is so called because it is left behind by families - कुल्मार्षाः कुलेषु सीदन्ति
4. ‘नु’ (nu) has many meanings:
b. In “कथं नु करिष्यति” (how pray will he do it?), “नन्वेतदकार्षीत्” (has he really done it?) - it is used for asking a question (अनुपृष्ट)
c. In - “वृक्षस्य नु ते पुरुहूत् वयाः” (Of thee like the branches of a tree) - it is used in a sense of comparison (उपमार्थ)

'शाखा' (śākhā, branches) are so called because they rest in the sky - शाखाः खशयाः
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